The Botanic Garden Volume I Part 20

The dispute among philosophers about phlogiston is not concerning the existence of an inflammable principle, but rather whether there be one or more inflammable principles. The disciples of Stahl, which till lately included the whole chemical world, believed in the ident.i.ty of phlogiston in all bodies which would flame or calcine. The disciples of Lavoisier pay homage to a plurality of phlogistons under the various names of charcoal, sulphur, metals, &c. Whatever will unite with _pure_ air, and thence compose an acid, is esteemed in this ingenious theory to be a different kind of phlogistic or inflammable body. At the same time there remains a doubt whether these inflammable bodies, as metals, sulphur, charcoal, &c. may not be compounded of the same phlogiston along with some other material yet undiscovered, and thus an unity of phlogiston exist, as in the theory of Stahl, though very differently applied in the explication of chemical phenomena.

Some modern philosophers are of opinion that the sun is the great fountain from which the earth and other planets derive all the phlogiston which they possess; and that this is formed by the combination of the solar rays with all opake bodies, but particularly with the leaves of vegetables, which they suppose to be organs adapted to absorb them. And that as animals receive their nourishment from vegetables they also obtain in a secondary manner their phlogiston from the sun. And lastly as great ma.s.ses of the mineral kingdom, which have been found in the thin crust of the earth which human labour has penetrated, have evidently been formed from the recrements of animal and vegetable bodies, these also are supposed thus to have derived their phlogiston from the sun.

Another opinion concerning the sun's rays is, that they are not luminous till they arrive at our atmosphere; and that there uniting with some part of the air they produce combustion, and light is emitted, and that an etherial acid, yet undiscovered, is formed from this combustion.

The more probable opinion is perhaps, that the sun is a phlogistic ma.s.s of matter, whose surface is in a state of combustion, which like other burning bodies emits light with immense velocity in all directions; that these rays of light act upon all opake bodies, and combining with them either displace or produce their elementary heat, and become chemically combined with the phlogistic part of them; for light is given out when phlogistic bodies unite with the oxygenous principle of the air, as in combustion, or in the reduction of metallic calxes; thus in presenting to the flame of a candle a letter-wafer, (if it be coloured with red- lead,) at the time the red-lead becomes a metallic drop, a flash of light is perceived. Dr. Alexander Wilson very ingeniously endeavours to prove that the sun is only in a state of combustion on its surface, and that the dark spots seen on the disk are excavations or caverns through the luminous crust, some of which are 4000 miles in diameter. Phil.

Trans. 1774. Of this I shall have occasion to speak again.

NOTE VI.--CENTRAL FIRES.

_Round her still centre tread the burning soil, And watch the billowy Lavas, as they boil._

CANTO I. l. 139.

M. de Mairan in a paper published in the Histoire de l'Academie de Sciences, 1765, has endeavoured to shew that the earth receives but a small part of the heat which it possesses, from the sun's rays, but is princ.i.p.ally heated by fires within itself. He thinks the sun is the cause of the vicissitudes of our seasons of summer and winter by a very small quant.i.ty of heat in addition to that already residing in the earth, which by emanations from the centre to the circ.u.mference renders the surface habitable, and without which, though the sun was constantly to illuminate two thirds of the globe at once, with a heat equal to that at the equator, it would soon become a ma.s.s of solid ice. His reasonings and calculations on this subject are too long and too intricate to be inserted here, but are equally curious and ingenious and carry much conviction along with them.

The opinion that the center of the earth consists of a large ma.s.s of burning lava, has been espoused by Boyle, Boerhave, and many other philosophers. Some of whom considering its supposed effects on vegetation and the formation of minerals have called it a second sun.

There are many arguments in support of this opinion, 1. Because the power of the sun does not extend much beyond ten feet deep into the earth, all below being in winter and summer always of the same degree of heat, viz. 48, which being much warmer than the mildest frost, is supposed to be sustained by some internal distant fire. Add to this however that from experiments made some years ago by Dr. Franklin the spring-water at Philadelphia appeared to be of 52 of heat, which seems further to confirm this opinion, since the climates in North America are supposed to be colder than those of Europe under similar degrees of lat.i.tude. 2. Mr. De Luc in going 1359 feet perpendicular into the mines of Hartz on July the 5th, 1778, on a very fine day found the air at the bottom a little warmer than at the top of the shaft. Phil. Trans. Vol.

LXIX. p. 488. In the mines in Hungary, which are 500 cubits deep, the heat becomes very troublesome when the miners get below 480 feet depth.

_Morinus de Locis subter_. p. 131. But as some other deep mines as mentioned by Mr. Kirwan are said to possess but the common heat of the earth; and as the crust of the globe thus penetrated by human labour is so thin compared with the whole, no certain deduction can be made from these facts on either side of the question. 3. The warm-springs in many parts of the earth at great distance from any Volcanos seem to originate from the condensation of vapours arising from water which is boiled by subterraneous fires, and cooled again in their pa.s.sage through a certain length of the colder soil; for the theory of chemical solution will not explain the equality of their heat at all seasons and through so many centuries. See note on Fucus in Vol. II. See a letter on this subject in Mr. Pilkinton's View of Derbys.h.i.+re from Dr. Darwin. 4. From the situations of volcanos which are always found upon the summit of the highest mountains. For as these mountains have been lifted up and lose several of their uppermost strata as they rise, the lowest strata of the earth yet known appear at the tops of the highest hills; and the beds of the Volcanos upon these hills must in consequence belong to the lowest strata of the earth, consisting perhaps of granite or basaltes, which were produced before the existance of animal or vegetable bodies, and might const.i.tute the original nucleus of the earth, which I have supposed to have been projected from the sun, hence the volcanos themselves appear to be spiracula or chimneys belonging to great central fires. It is probably owing to the escape of the elastic vapours from these spiracula that the modern earthquakes are of such small extent compared with those of remote antiquity, of which the vestiges remain all over the globe. 5. The great size and height of the continents, and the great size and depth of the South-sea, Atlantic, and other oceans, evince that the first earthquakes, which produced these immense changes in the globe, must have been occasioned by central fires. 6. The very distant and expeditious communication of the shocks of some great earthquakes. The earthquake at Lisbon in 1755 was perceived in Scotland, in the Peak of Derbys.h.i.+re, and in many other distant parts of Europe.

The percussions of it travelled with about the velocity of sound, viz.

about thirteen miles in a minute. The earthquake in 1693 extended 2600 leagues. (Goldsmith's History.) These phenomena are easily explained if the central parts of the earth consist of a fluid lava, as a percussion on one part of such a fluid ma.s.s would be felt on other parts of its confining vault, like a stroke on a fluid contained in a bladder, which however gentle on one side is perceptible to the hand placed on the other; and the velocity with which such a concussion would travel would be that of sound, or thirteen miles in a minute. For further information on this part of the subject the reader is referred to Mr. Mich.e.l.l's excellent Treatise on Earthquakes in the Philos. Trans. Vol. LI. 7. That there is a cavity at the center of the earth is made probable by the late experiments on the attraction of mountains by Mr. Maskerlyne, who supposed from other considerations that the density of the earth near the surface should be five times less than its mean density. Phil.

Trans. Vol. LXV. p. 498. But found from the attraction of the mountain Schehallien, that it is probable, the mean density of the earth is but double that of the hill. Ibid. p. 532. Hence if the first supposition be well founded there would appear to be a cavity at the centre of considerable magnitude, from whence the immense beds and mountains of lava, toadstone, basaltes, granite, &c. have been protruded. 8. The variation of the compa.s.s can only be accounted for by supposing the central parts of the earth to consist of a fluid ma.s.s, and that part of this fluid is iron, which requiring a greater degree of heat to bring it into fusion than gla.s.s or other metals, remains a solid, and the vis inertiae of this fluid ma.s.s with the iron in it, occasions it to perform fewer revolutions than the crust of solid earth over it, and thus it is gradually left behind, and the place where the floating iron resides is pointed to by the direct or retrograde motions of the magnetic needle.

This seems to have been nearly the opinion of Dr. Halley and Mr. Euler.

NOTE VII.--ELEMENTARY HEAT.

_Or sphere on sphere in widening waves expand, And glad with genial warmth the inc.u.mbent land._

CANTO I. l. 143.

A certain quant.i.ty of heat seems to be combined with all bodies besides the sensible quant.i.ty which gravitates like the electric fluid amongst them. This combined heat or latent heat of Dr. Black, when set at liberty by fermentation, inflammation, crystallization, freezing, or other chemical attractions producing new _combinations_, pa.s.ses as a fluid element into the surrounding bodies. And by thawing, diffusion of neutral salts in water, melting, and other chemical _solutions_, a portion of heat is attracted from the bodies in vicinity and enters into or becomes combined with the new solutions.

Hence a _combination_ of metals with acids, of essential oils and acids, of alcohol and water, of acids and water, give out heat; whilst a _solution_ of snow in water or in acids, and of neutral salts in water, attract heat from the surrounding bodies. So the acid of nitre mixed with oil of cloves unites with it and produces a most violent flame; the same acid of nitre poured on snow instantly dissolves it and produces the greatest degree of cold yet known, by which at Petersburgh quicksilver was first frozen in 1760.

Water may be cooled below 32 without being frozen, if it be placed on a solid floor and secured from agitation, but when thus cooled below the freezing point the least agitation turns part of it suddenly into ice, and when this sudden freezing takes place a thermometer placed in it instantly rises as some heat is given out in the act of congelation, and the ice is thus left with the same _sensible_ degree of cold as the water had possessed before it was agitated, but is nevertheless now combined with less _latent_ heat.

A cubic inch of water thus cooled down to 32 mixed with an equal quant.i.ty of boiling water at 212 will cool it to the middle number between these two, or to 122. But a cubic inch of ice whose sensible cold also is but 32, mixed with an equal quant.i.ty of boiling water, will cool it six times as much as the cubic inch of cold water above-mentioned, as the ice not only gains its share of the sensible or gravitating heat of the boiling water but attracts to itself also and combines with the quant.i.ty of latent heat which it had lost at the time of its congelation.

So boiling water will acquire but 212 of heat under the common pressure of the atmosphere, but the steam raised from it by its expansion or by its solution in the atmosphere combines with and carries away a prodigious quant.i.ty of heat which it again parts with on its condensation; as is seen in common distillation where the large quant.i.ty of water in the worm-tub is so soon heated. Hence the evaporation of ether on a thermometer soon sinks the mercury below freezing, and hence a warmth of the air in winter frequently succeeds a shower.

When the matter of heat or calorique is set at liberty from its combinations, as by inflammation, it pa.s.ses into the surrounding bodies, which possess different capacities of acquiring their share of the loose or sensible heat; thus a pint measure of cold water at 48 mixed with a pint of boiling water at 212 will cool it to the degree between these two numbers, or to 154, but it requires two pint measures of quicksilver at 48 of heat to cool one pint of water as above. These and other curious experiments are adduced by Dr. Black to evince the existance of combined or latent heat in bodies, as has been explained by some of his pupils, and well ill.u.s.trated by Dr. Crawford. The world has long been in expectation of an account of his discoveries on this subject by the celebrated author himself.

As this doctrine of elementary heat in its fluid and combined state is not yet universally received, I shall here add two arguments in support of it drawn from different sources, viz. from the heat given out or absorbed by the mechanical condensation or expansion of the air, and perhaps of other bodies, and from the a.n.a.logy of the various phenomena of heat with those of electricity.

I. If a thermometer be placed in the receiver of an air-pump, and the air hastily exhausted, the thermometer will sink some degrees, and the gla.s.s become steamy; the same occurs in hastily admitting a part of the air again. This I suppose to be produced by the expansion of part of the air, both during the exhaustion and re-admission of it; and that the air so expanded becomes capable of attracting from the bodies in its vicinity a part of their heat, hence the vapours contained in it and the gla.s.s receiver are for a time colder and the steam is precipitated. That the air thus parts with its moisture from the cold occasioned by its rarefaction and not simply by the rarefaction itself is evident, because in a minute or two the same rarefied air will again take up the dew deposited on the receiver; and because water will evaporate sooner in rare than in dense air.

There is a curious phenomenon similar to this observed in the fountain of Hiero constructed on a large scale at the Chemnicensian mines in Hungary. In this machine the air in a large vessel is compressed by a column of water 260 feet high, a stop-c.o.c.k is then opened, and as the air issues out with great vehemence, and thus becomes immediately greatly expanded, so much cold is produced that the moisture from this stream of air is precipitated in the form of snow, and ice is formed adhering to the nosel of the c.o.c.k. This remarkable circ.u.mstance is described at large with a plate of the machine in Philos. Trans. Vol.

LII. for 1761.

The following experiment is related by Dr. Darwin in the Philos. Trans.

Vol. LXXVIII. Having charged an air-gun as forcibly as he well could the air-cell and syringe became exceedingly hot, much more so than could be ascribed to the friction in working it; it was then left about half an hour to cool down to the temperature of the air, and a thermometer having been previously fixed against a wall, the air was discharged in a continual stream on its bulb, and it sunk many degrees. From these three experiments of the steam in the exhausted receiver being deposited and re-absorbed, when a part of the air is exhausted or re-admitted, and the snow produced by the fountain of Hiero, and the extraordinary heat given out in charging, and the cold produced in discharging an air-gun, there is reason to conclude that when air is mechanically compressed the elementary fluid heat is pressed out of it, and that when it is mechanically expanded the same fluid heat is re-absorbed from the common ma.s.s.

It is probable all other bodies as well as air attract heat from their neighbours when they are mechanically expanded, and give it out when they are mechanically condensed. Thus when a vibration of the particles of hard bodies is excited by friction or by percussion, these particles mutually recede from and approach each other reciprocally; at the times of their recession from each other, the body becomes enlarged in bulk, and is then in a condition to attract heat from those in its vicinity with great and sudden power; at the times of their approach to each other this heat is again given out, but the bodies in contact having in the mean while received the heat they had thus lost, from other bodies behind them, do not so suddenly or so forcibly re-absorb the heat again from the body in vibration; hence it remains on its surface like the electric fluid on a rubbed gla.s.s globe, and for the same reason, because there is no good conductor to take it up again. Hence at every vibration more and more heat is acquired and stands loose upon the surface; as in filing metals or rubbing gla.s.s tubes; and thus a smith with a few strokes on a nail on his anvil can make it hot enough to light a brimstone-match; and hence in striking flint and steel together heat enough is produced to vitrify the parts thus strucken off, the quant.i.ty of which heat is again probably increased by the new chemical combination.

II. The a.n.a.logy between the phenomena of the electric fluid and of heat furnishes another argument in support of the existence of heat as a gravitating fluid. 1. They are both acc.u.mulated by friction on the excited body. 2. They are propagated easily or with difficalty along the same cla.s.ses of bodies; with ease by metals, with less ease by water; and with difficulty by resins, bees-wax, silk, air, and gla.s.s. Thus gla.s.s canes or canes of sealing-wax may be melted by a blow-pipe or a candle within a quarter of an inch of the fingers which hold them, without any inconvenient heat, while a pin or other metallic substance applyed to the flame of a candle so readily conducts the heat as immediately to burn the fingers. Hence clothes of silk keep the body warmer than clothes of linen of equal thickness, by confining the heat upon the body. And hence plains are so much warmer than the summits of mountains by the greater density of the air confining the acquired heat upon them. 3. They both give out light in their pa.s.sage through air, perhaps not in their pa.s.sage through a vacuum. 4. They both of them fuse or vitrify metals. 5. Bodies after being electrized if they are mechanically extended will receive a greater quant.i.ty of electricity, as in Dr. Franklin's experiment of the chain in the tankard; the same seems true in respect to heat as explained above. 6. Both heat and electricity contribute to suspend steam in the atmosphere by producing or increasing the repulsion of its particles. 7. They both gravitate, when they have been acc.u.mulated, till they find their equilibrium.

If we add to the above the many chemical experiments which receive an easy and elegant explanation from the supposed matter of heat, as employed in the works of Bergman and Lavoisier, I think we may reasonably allow of its existence as an element, occasionally combined with other bodies, and occasionally existing as a fluid, like the electric fluid gravitating amongst them, and that hence it may be propagated from the central fires of the earth to the whole ma.s.s, and contribute to preserve the mean heat of the earth, which in this country is about 48 degrees but variable from the greater or less effect of the sun's heat in different climates, so well explained in Mr. Kirwan's Treatise on the Temperature of different Lat.i.tudes. 1787, Elmsly.

London.

NOTE VIII.--MEMNON'S LYRE.

_So to the sacred Sun in Memnon's fane Spontaneous concords quired the matin strain._

CANTO I. l. 183.

The gigantic statue of Memnon in his temple at Thebes had a lyre in his hands, which many credible writers a.s.sure us, sounded when the rising sun shone upon it. Some philosophers have supposed that the sun's light possesses a mechanical impulse, and that the sounds abovementioned might be thence produced. Mr. Mich.e.l.l constructed a very tender horizontal balance, as related by Dr. Priestley in his history of light and colours, for this purpose, but some experiments with this balance which I saw made by the late Dr. Powel, who threw the focus of a large reflector on one extremity of it, were not conclusive either way, as the copper leaf of the balance approached in one experiment and receded in another.

There are however methods by which either a rotative or alternating motion may be produced by very moderate degrees of heat. If a straight gla.s.s tube, such as are used for barometers, be suspended horizontally before a fire, like a roasting spit, it will revolve by intervals; for as gla.s.s is a bad conductor of heat the side next the fire becomes heated sooner than the opposite side, and the tube becomes bent into a bow with the external part of the curve towards the fire, this curve then falls down and produces a fourth part of a revolution of the gla.s.s tube, which thus revolves with intermediate pauses.

Another alternating motion I have seen produced by suspending a gla.s.s tube about eight inches long with bulbs at each end on a centre like a scale beam. This curious machine is filled about one third part with purest spirit of wine, the other two thirds being a vacuum, and is called a pulse-gla.s.s, if it be placed in a box before the fire, so that either bulb, as it rises, may become shaded from the fire, and exposed to it when it descends, an alternate libration of it is produced. For spirit of wine in vacuo emits steam by a very small degree of heat, and this steam forces the spirit beneath it up into the upper bulb, which therefore descends. It is probable such a machine on a larger scale might be of use to open the doors or windows of hot-houses or mellon- frames, when the air within them should become too much heated, or might be employed in more important mechanical purposes.

On travelling through a hot summer's day in a chaise with a box covered with leather on the fore-axle-tree, I observed, as the sun shone upon the black leather, the box began to open its lid, which at noon rose above a foot, and could not without great force be pressed down; and which gradually closed again as the sun declined in the evening. This I suppose might with still greater facility be applied to the purpose of opening melon-frames or the sashes of hot-houses.

The statue of Memnon was overthrown and sawed in two by Cambyses to discover its internal structure, and is said still to exist. See Savary's Letters on Egypt. The truncated statue is said for many centuries to have saluted the rising sun with chearful tones, and the setting sun with melancholy ones.

NOTE IX.--LUMINOUS INSECTS.

_Star of the earth, and diamond of the night._