Familiar Letters on Chemistry Part 2

Professor Weber of Gottingen has thrown out a suggestion, that if a contrivance could be devised to enable us to convert at will the wheels of the steam-carriage into magnets, we should be enabled to ascend and descend acclivities with great facility. This notion may ultimately be, to a certain extent, realised.

The employment of the galvanic pile as a motory power, however, must, like every other contrivance, depend upon the question of its relative economy: probably some time hence it may so far succeed as to be adopted in certain favourable localities; it may stand in the same relation to steam power as the manufacture of beet sugar bears to that of cane, or as the production of gas from oils and resins to that from mineral coal.

The history of beet-root sugar affords us an excellent ill.u.s.tration of the effect of prices upon commercial productions. This branch of industry seems at length, as to its processes, to be perfected. The most beautiful white sugar is now manufactured from the beet-root, in the place of the treacle-like sugar, having the taste of the root, which was first obtained; and instead of 3 or 4 per cent., the proportion obtained by Achard, double or even treble that amount is now produced. And notwithstanding the perfection of the manufacture, it is probable it will ere long be in most places entirely discontinued. In the years 1824 to 1827, the prices of agricultural produce were much lower than at present, while the price of sugar was the same. At that time one malter [1] of wheat was 10s., and one klafter [2] of wood 18s., and land was falling in price. Thus, food and fuel were cheap, and the demand for sugar unlimited; it was, therefore, advantageous to grow beet-root, and to dispose of the produce of land as sugar. All these circ.u.mstances are now different.

A malter of wheat costs 18s.; a klafter of wood, 30s. to 36s. Wages have risen, but not in proportion, whilst the price of colonial sugar has fallen. Within the limits of the German commercial league, as, for instance, at Frankfort-on-the-Maine, a pound of the whitest and best loaf sugar is 7d.; the import duty is 31/d., or 30s. per cwt., leaving 31/d. as the price of the sugar. In the year 1827, then, one malter of wheat was equal to 40 lbs. weight of sugar, whilst at present that quant.i.ty of wheat is worth 70 lbs. of sugar.

If indeed fuel were the same in price as formerly, and 70 lbs. of sugar could be obtained from the same quant.i.ty of the root as then yielded 40 lbs., it might still be advantageously produced; but the amount, if now obtained by the most approved methods of extraction, falls far short of this; and as fuel is double the price, and labour dearer, it follows that, at present, it is far more advantageous to cultivate wheat and to purchase sugar.

There are, however, other elements which must enter into our calculations; but these serve to confirm our conclusion that the manufacture of beet-root sugar as a commercial speculation must cease. The leaves and residue of the root, after the juice was expressed, were used as food for cattle, and their value naturally increased with the price of grain. By the process formerly pursued, 75 lbs. weight of juice were obtained from 100 lbs. of beet-root, and gave 5 lbs. of sugar. The method of Schutzenbach, which was eagerly adopted by the manufacturers, produced from the same quant.i.ty of root 8 lbs. of sugar; but it was attended with more expense to produce, and the loss of the residue as food for cattle.

The increased expense in this process arises from the larger quant.i.ty of fuel required to evaporate the water; for instead of merely evaporating the juice, the dry residue is treated with water, and we require fuel sufficient to evaporate 106 lbs. of fluid instead of 75 lbs., and the residue is only fit for manure. The additional 3 lbs. of sugar are purchased at the expense of much fuel, and the loss of the residue as an article of food.

If the valley of the Rhine possessed mines of diamonds as rich as those of Golconda, Visiapoor, or the Brazils, they would probably not be worth the working: at those places the cost of extraction is 28s. to 30s. the carat. With us it amounts to three or four times as much--to more, in fact, than diamonds are worth in the market. The sand of the Rhine contains gold; and in the Grand Duchy of Baden many persons are occupied in gold-was.h.i.+ng when wages are low; but as soon as they rise, this employment ceases. The manufacture of sugar from beet-root, in the like manner, twelve to fourteen years ago offered advantages which are now lost: instead, therefore, of maintaining it at a great sacrifice, it would be more reasonable, more in accordance with true natural economy, to cultivate other and more valuable productions, and with them purchase sugar. Not only would the state be the gainer, but every member of the community.

This argument does not apply, perhaps, to France and Bohemia, where the prices of fuel and of colonial sugar are very different to those in Germany.

The manufacture of gas for lighting, from coal, resin, and oils, stands with us on the same barren ground.

The price of the materials from which gas is manufactured in England bears a direct proportion to the price of corn: there the cost of tallow and oil is twice as great as in Germany, but iron and coal are two-thirds cheaper; and even in England the manufacture of gas is only advantageous when the other products of the distillation of coal, the c.o.ke, &c., can be sold.

It would certainly be esteemed one of the greatest discoveries of the age if any one could succeed in condensing coal gas into a white, dry, solid, odourless substance, portable, and capable of being placed upon a candlestick, or burned in a lamp. Wax, tallow, and oil, are combustible gases in a solid or fluid form, which offer many advantages for lighting, not possessed by gas: they furnish, in well-constructed lamps, as much light, without requiring the expensive apparatus necessary for the combustion of gas, and they are generally more economical. In large towns, or such establishments as hotels, where c.o.ke is in demand, and where losses in stolen tallow or oil must be considered, together with the labour of snuffing candles and cleaning lamps, the higher price of gas is compensated.

In places where gas can be manufactured from resin, oil of turpentine, and other cheap oils, as at Frankfort, this is advantageous so long as it is pursued on small scale only. If large towns were lighted in the same manner, the materials would rise in price: the whole amount at present produced would scarcely suffice for two such towns as Berlin and Munich. But no just calculation can be made from the present prices of turpentine, resin, &c., which are not produced upon any large scale.

[Footnote 1: Malter--a measure containing several bushels, but varying in different countries.]

[Footnote 2: Klafter--a cord, a stack, measuring six feet every way.]

LETTER V

My dear Sir,

Until very recently it was supposed that the physical qualities of bodies, i.e. hardness, colour, density, transparency, &c., and still more their chemical properties, must depend upon the nature of their elements, or upon their composition. It was tacitly received as a principle, that two bodies containing the same elements in the same proportion, must of necessity possess the same properties. We could not imagine an exact ident.i.ty of composition giving rise to two bodies entirely different in their sensible appearance and chemical relations. The most ingenious philosophers entertained the opinion that chemical combination is an inter-penetration of the particles of different kinds of matter, and that all matter is susceptible of infinite division. This has proved to be altogether a mistake. If matter were infinitely divisible in this sense, its particles must be imponderable, and a million of such molecules could not weigh more than an infinitely small one. But the particles of that imponderable matter, which, striking upon the retina, give us the sensation of light, are not in a mathematical sense infinitely small.

Inter-penetration of elements in the production of a chemical compound, supposes two distinct bodies, A and B, to occupy one and the same s.p.a.ce at the same time. If this were so, different properties could not consist with an equal and identical composition.

That hypothesis, however, has shared the fate of innumerable imaginative explanations of natural phenomena, in which our predecessors indulged. They have now no advocate. The force of truth, dependent upon observation, is irresistible. A great many substances have been discovered amongst organic bodies, composed of the same elements in the same relative proportions, and yet exhibiting physical and chemical properties perfectly distinct one from another. To such substances the term Isomeric (from 1/ao1/ equal and aei1/o1/ part) is applied. A great cla.s.s of bodies, known as the volatile oils, oil of turpentine, essence of lemons, oil of balsam of copaiba, oil of rosemary, oil of juniper, and many others, differing widely from each other in their odour, in their medicinal effects, in their boiling point, in their specific gravity, &c., are exactly identical in composition,--they contain the same elements, carbon and hydrogen, in the same proportions.

How admirably simple does the chemistry of organic nature present itself to us from this point of view! An extraordinary variety of compound bodies produced with equal weights of two elements! and how wide their dissimilarity! The crystallised part of the oil of roses, the delicious fragrance of which is so well known, a solid at ordinary temperatures, although readily volatile, is a compound body containing exactly the same elements, and in the same proportions, as the gas we employ for lighting our streets; and, in short, the same elements, in the same relative quant.i.ties, are found in a dozen other compounds, all differing essentially in their physical and chemical properties.

These remarkable truths, so highly important in their applications, were not received and admitted as sufficiently established, without abundant proofs. Many examples have long been known where the a.n.a.lysis of two different bodies gave the same composition; but such cases were regarded as doubtful: at any rate, they were isolated observations, homeless in the realms of science: until, at length, examples were discovered of two or more bodies whose absolute ident.i.ty of composition, with totally distinct properties, could be demonstrated in a more obvious and conclusive manner than by mere a.n.a.lysis; that is, they can be converted and reconverted into each other without addition and without subtraction.

In cyanuric acid, hydrated cyanic acid, and cyamelide, we have three such isomeric compounds.

Cyanuric acid is crystalline, soluble in water, and capable of forming salts with metallic oxides.

Hydrated cyanic acid is a volatile and highly blistering fluid, which cannot be brought into contact with water without being instantaneously decomposed.

Cyamelide is a white substance very like porcelain, absolutely insoluble in water.

Now if we place the first,--cyanuric acid,--in a vessel hermetically sealed, and apply a high degree of heat, it is converted by its influence into hydrated cyanic acid; and, then, if this is kept for some time at the common temperature, it pa.s.ses into cyamelide, no other element being present. And, again inversely, cyamelide can be converted into cyanuric acid and hydrated cyanic acid.

We have three other bodies which pa.s.s through similar changes, in aldehyde, metaldehyde, and etaldehyde; and, again two, in urea and cyanuret of ammonia. Further, 100 parts of aldehyde hydrated butyric acid and acetic ether contain the same elements in the same proportion. Thus one substance may be converted into another without addition or subtraction, and without the partic.i.p.ation of any foreign bodies in the change.

The doctrine that matter is not infinitely divisible, but on the contrary, consists of atoms incapable of further division, alone furnishes us with a satisfactory explanation of these phenomena. In chemical combinations, the ultimate atoms of bodies do not penetrate each other, they are only arranged side by side in a certain order, and the properties of the compound depend entirely upon this order.

If they are made to change their place--their mode of arrangement--by an impulse from without, they combine again in a different manner, and another compound is formed with totally different properties. We may suppose that one atom combines with one atom of another element to form a compound atom, while in other bodies two and two, four and four, eight and eight, are united; so that in all such compounds the amount per cent. of the elements is absolutely equal; and yet their physical and chemical properties must be totally different, the const.i.tution of each atom being peculiar, in one body consisting of two, in another of four, in a third of eight, and in a fourth of sixteen simple atoms.

The discovery of these facts immediately led to many most beautiful and interesting results; they furnished us with a satisfactory explanation of observations which were before veiled in mystery,--a key to many of Nature's most curious recesses.

Again; solid bodies, whether simple or compound, are capable of existing in two states, which are known by the terms amorphous and crystalline.

When matter is pa.s.sing from a gaseous or liquid state slowly into a solid, an incessant motion is observed, as if the molecules were minute magnets; they are seen to repel each other in one direction, and to attract and cohere together in another, and in the end become arranged into a regular form, which under equal circ.u.mstances is always the same for any given kind of matter; that is, crystals are formed.

Time and freedom of motion for the particles of bodies are necessary to the formation of crystals. If we force a fluid or a gas to become suddenly solid, leaving no time for its particles to arrange themselves, and cohere in that direction in which the cohesive attraction is strongest, no crystals will be formed, but the resulting solid will have a different colour, a different degree of hardness and cohesion, and will refract light differently; in one word, will be amorphous. Thus we have cinnabar as a red and a jet-black substance; sulphur a fixed and brittle body, and soft, semitransparent, and ductile; gla.s.s as a milk-white opaque substance, so hard that it strikes fire with steel, and in its ordinary and well-known state. These dissimilar states and properties of the same body are occasioned in one case by a regular, in the other by an irregular, arrangement of its atoms; one is crystalline, the other amorphous.

Applying these facts to natural productions, we have reason to believe that clay-slate, and many kinds of greywacke, are amorphous feldspar, as transition limestone is amorphous marble, basalt and lava mixtures of amorphous zeolite and augite. Anything that influences the cohesion, must also in a certain degree alter the properties of bodies. Carbonate of lime, if crystallised at ordinary temperatures, possesses the crystalline form, hardness, and refracting power of common spar; if crystallised at a higher temperature, it has the form and properties of arragonite.

Finally, Isomorphism, or the equality of form of many chemical compounds having a different composition, tends to prove that matter consists of atoms the mere arrangement of which produces all the properties of bodies. But when we find that a different arrangement of the same elements gives rise to various physical and chemical properties, and a similar arrangement of different elements produces properties very much the same, may we not inquire whether some of those bodies which we regard as elements may not be merely modifications of the same substance?--whether they are not the same matter in a different state of arrangement? We know in fact the existence of iron in two states, so dissimilar, that in the one, it is to the electric chain like platinum, and in the other it is like zinc; so that powerful galvanic machines have been constructed of this one metal.

Among the elements are several instances of remarkable similarity of properties. Thus there is a strong resemblance between platinum and iridium; bromine and iodine; iron, manganese, and magnesium; cobalt and nickel; phosphorus and a.r.s.enic; but this resemblance consists mainly in their forming isomorphous compounds in which these elements exist in the same relative proportion. These compounds are similar, because the atoms of which they are composed are arranged in the same manner. The converse of this is also true: nitrate of strontia becomes quite dissimilar to its common state if a certain proportion of water is taken into its composition.

If we suppose selenium to be merely modified sulphur, and phosphorus modified a.r.s.enic, how does it happen, we must inquire, that sulphuric acid and selenic acid, phosphoric and a.r.s.enic acid, respectively form compounds which it is impossible to distinguish by their form and solubility? Were these merely isomeric, they ought to exhibit properties quite dissimilar!

We have not, I believe, at present the remotest ground to suppose that any one of those substances which chemists regard as elements can be converted into another. Such a conversion, indeed, would presuppose that the element was composed of two or more ingredients, and was in fact not an element; and until the decomposition of these bodies is accomplished, and their const.i.tuents discovered, all pretensions to such conversions deserve no notice.

Dr. Brown of Edinburgh thought he had converted iron into rhodium, and carbon or paracyanogen into silicon. His paper upon this subject was published in the Transactions of the Royal Society of Edinburgh, and contained internal evidence, without a repet.i.tion of his experiments, that he was totally unacquainted with the principles of chemical a.n.a.lysis. But his experiments have been carefully repeated by qualified persons, and they have completely proved his ignorance: his rhodium is iron, and his silicon an impure incombustible coal.

LETTER VI

My dear Sir,

One of the most remarkable effects of the recent progress of science is the alliance of chemistry with physiology, by which a new and unexpected light has been thrown upon the vital processes of plants and animals. We have now no longer any difficulty in understanding the different actions of aliments, poisons, and remedial agents--we have a clear conception of the causes of hunger, of the exact nature of death; and we are not, as formerly, obliged to content ourselves with a mere description of their symptoms. It is now ascertained with positive certainty, that all the substances which const.i.tute the food of man must be divided into two great cla.s.ses, one of which serves for the nutrition and reproduction of the animal body, whilst the other ministers to quite different purposes. Thus starch, gum, sugar, beer, wine, spirits, &c., furnish no element capable of entering into the composition of blood, muscular fibre, or any part which is the seat of the vital principle. It must surely be universally interesting to trace the great change our views have undergone upon these subjects, as well as to become acquainted with the researches from which our present knowledge is derived.

The primary conditions of the maintenance of animal life, are a constant supply of certain matters, animal food, and of oxygen, in the shape of atmospheric air. During every moment of life, oxygen is absorbed from the atmosphere in the organs of respiration, and the act of breathing cannot cease while life continues.

The observations of physiologists have demonstrated that the body of an adult man supplied abundantly with food, neither increases nor diminishes in weight during twenty-four hours, and yet the quant.i.ty of oxygen absorbed into his system, in that period, is very considerable. According to the experiments of Lavoisier, an adult man takes into his system from the atmosphere, in one year, no less than 746 pounds weight of oxygen; the calculations of Menzies make the quant.i.ty amount even to 837 pounds; but we find his weight at the end of the year either exactly the same or different one way or the other by at most a few pounds. What, it may be asked, has become of the enormous amount of oxygen thus introduced into the human system in the course of one year? We can answer this question satisfactorily. No part of the oxygen remains in the body, but is given out again, combined with carbon and hydrogen. The carbon and hydrogen of certain parts of the animal body combine with the oxygen introduced through the lungs and skin, and pa.s.s off in the forms of carbonic acid and vapour of water. At every expiration and every moment of life, a certain amount of its elements are separated from the animal organism, having entered into combination with the oxygen of the atmosphere.

In order to obtain a basis for the approximate calculation, we may a.s.sume, with Lavoisier and Seguin, that an adult man absorbs into his system 32 1/2 ounces of oxygen daily,--that is, 46,037 cubic inches = 15,661 grains, French weight; and further, that the weight of the whole ma.s.s of his blood is 24 pounds, of which 80 per cent.

is water. Now, from the known composition of the blood, we know that in order to convert its whole amount of carbon and hydrogen into carbonic acid and water, 64.102 grains of oxygen are required. This quant.i.ty will be taken into the system in four days and five hours.

Whether the oxygen enters into combination directly with the elements of the blood, or with the carbon and hydrogen of other parts of the body, it follows inevitably--the weight of the body remaining unchanged and in a normal condition--that as much of these elements as will suffice to supply 24 pounds of blood, must be taken into the system in four days and five hours; and this necessary amount is furnished by the food.

We have not, however, remained satisfied with mere approximation: we have determined accurately, in certain cases, the quant.i.ty of carbon taken daily in the food, and of that which pa.s.ses out of the body in the faeces and urine combined--that is, uncombined with oxygen; and from these investigations it appears that an adult man taking moderate exercise consumes 13.9 ounces of carbon, which pa.s.s off through the skin and lungs as carbonic acid gas. [1]

It requires 37 ounces of oxygen to convert 13 9/10 of carbon into carbonic acid. Again; according to the a.n.a.lysis of Boussingault, (Annales de Chim. et de Phys., lxx. i. p.136), a horse consumes 79 1/10 ounces of carbon in twenty-four hours, a milch cow 70 3/4 ounces; so that the horse requires 13 pounds 3 1/2 ounces, and the cow 11 pounds 10 3/4 ounces of oxygen. [2]