Faraday as a Discoverer Part 4
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The burst of power which had filled the four preceding years with an amount of experimental work unparalleled in the history of science partially subsided in 1835, and the only scientific paper contributed by Faraday in that year was a comparatively unimportant one, 'On an improved Form of the Voltaic Battery.' He brooded for a time: his experiments on electrolysis had long filled his mind; he looked, as already stated, into the very heart of the electrolyte, endeavouring to render the play of its atoms visible to his mental eye. He had no doubt that in this case what is called 'the electric current' was propagated from particle to particle of the electrolyte; he accepted the doctrine of decomposition and recomposition which, according to Grothuss and Davy, ran from electrode to electrode. And the thought impressed him more and more that ordinary electric induction was also transmitted and sustained by the action of 'contiguous particles.'
His first great paper on frictional electricity was sent to the Royal Society on November 30, 1837. We here find him face to face with an idea which beset his mind throughout his whole subsequent life,--the idea of action at a distance. It perplexed and bewildered him. In his attempts to get rid of this perplexity, he was often unconsciously rebelling against the limitations of the intellect itself. He loved to quote Newton upon this point; over and over again he introduces his memorable words, 'That gravity should be innate, inherent, and essential to matter, so that one body may act upon another at a distance through a vacuum and without the mediation of anything else, by and through which this action and force may be conveyed from one to another, is to me so great an absurdity, that I believe no man who has in philosophical matters a competent faculty of thinking, can ever fall into it. Gravity must be caused by an agent acting constantly according to certain laws; but whether this agent be material or immaterial, I have left to the consideration of my readers.'[1]
Faraday does not see the same difficulty in his contiguous particles.
And yet, by transferring the conception from ma.s.ses to particles, we simply lessen size and distance, but we do not alter the quality of the conception. Whatever difficulty the mind experiences in conceiving of action at sensible distances, besets it also when it attempts to conceive of action at insensible distances. Still the investigation of the point whether electric and magnetic effects were wrought out through the intervention of contiguous particles or not, had a physical interest altogether apart from the metaphysical difficulty. Faraday grapples with the subject experimentally. By simple intuition he sees that action at a distance must be exerted in straight lines. Gravity, he knows, will not turn a corner, but exerts its pull along a right line; hence his aim and effort to ascertain whether electric action ever takes place in curved lines. This once proved, it would follow that the action is carried on by means of a medium surrounding the electrified bodies. His experiments in 1837 reduced, in his opinion, this point of demonstration. He then found that he could electrify, by induction, an insulated sphere placed completely in the shadow of a body which screened it from direct action.
He pictured the lines of electric force bending round the edges of the screen, and reuniting on the other side of it; and he proved that in many cases the augmentation of the distance between his insulated sphere and the inducing body, instead of lessening, increased the charge of the sphere. This he ascribed to the coalescence of the lines of electric force at some distance behind the screen.
Faraday's theoretic views on this subject have not received general acceptance, but they drove him to experiment, and experiment with him was always prolific of results. By suitable arrangements he placed a metallic sphere in the middle of a large hollow sphere, leaving a s.p.a.ce of something more than half an inch between them. The interior sphere was insulated, the external one uninsulated. To the former he communicated a definite charge of electricity. It acted by induction upon the concave surface of the latter, and he examined how this act of induction was effected by placing insulators of various kinds between the two spheres. He tried gases, liquids, and solids, but the solids alone gave him positive results. He constructed two instruments of the foregoing description, equal in size and similar in form. The interior sphere of each communicated with the external air by a bra.s.s stem ending in a k.n.o.b. The apparatus was virtually a Leyden jar, the two coatings of which were the two spheres, with a thick and variable insulator between them. The amount of charge in each jar was determined by bringing a proof-plane into contact with its k.n.o.b and measuring by a torsion balance the charge taken away. He first charged one of his instruments, and then dividing the charge with the other, found that when air intervened in both cases the charge was equally divided. But when sh.e.l.lac, sulphur, or spermaceti was interposed between the two spheres of one jar, while air occupied this interval in the other, then he found that the instrument occupied by the 'solid dielectric' takes more than half the original charge. A portion of the charge was absorbed by the dielectric itself. The electricity took time to penetrate the dielectric. Immediately after the discharge of the apparatus, no trace of electricity was found upon its k.n.o.b. But after a time electricity was found there, the charge having gradually returned from the dielectric in which it had been lodged. Different insulators possess this power of permitting the charge to enter them in different degrees. Faraday figured their particles as polarized, and he concluded that the force of induction is propagated from particle to particle of the dielectric from the inner sphere to the outer one. This power of propagation possessed by insulators he called their 'Specific Inductive Capacity.'
Faraday visualizes with the utmost clearness the state of his contiguous particles; one after another they become charged, each succeeding particle depending for its charge upon its predecessor. And now he seeks to break down the wall of part.i.tion between conductors and insulators.
'Can we not,' he says, 'by a gradual chain of a.s.sociation carry up discharge from its occurrence in air through spermaceti and water, to solutions, and then on to chlorides, oxides, and metals, without any essential change in its character?' Even copper, he urges, offers a resistance to the transmission of electricity. The action of its particles differs from those of an insulator only in degree. They are charged like the particles of the insulator, but they discharge with greater ease and rapidity; and this rapidity of molecular discharge is what we call conduction. Conduction then is always preceded by atomic induction; and when, through some quality of the body which Faraday does not define, the atomic discharge is rendered slow and difficult, conduction pa.s.ses into insulation.
Though they are often obscure, a fine vein of philosophic thought runs through those investigations. The mind of the philosopher dwells amid those agencies which underlie the visible phenomena of Induction and Conduction; and he tries by the strong light of his imagination to see the very molecules of his dielectrics. It would, however, be easy to criticise these researches, easy to show the looseness, and sometimes the inaccuracy, of the phraseology employed; but this critical spirit will get little good out of Faraday. Rather let those who ponder his works seek to realise the object he set before him, not permitting his occasional vagueness to interfere with their appreciation of his speculations. We may see the ripples, and eddies, and vortices of a flowing stream, without being able to resolve all these motions into their const.i.tuent elements; and so it sometimes strikes me that Faraday clearly saw the play of fluids and ethers and atoms, though his previous training did not enable him to resolve what he saw into its const.i.tuents, or describe it in a manner satisfactory to a mind versed in mechanics. And then again occur, I confess, dark sayings, difficult to be understood, which disturb my confidence in this conclusion. It must, however, always be remembered that he works at the very boundaries of our knowledge, and that his mind habitually dwells in the 'boundless contiguity of shade' by which that knowledge is surrounded.
In the researches now under review the ratio of speculation and reasoning to experiment is far higher than in any of Faraday's previous works. Amid much that is entangled and dark we have flashes of wondrous insight and utterances which seem less the product of reasoning than of revelation. I will confine myself here to one example of this divining power. By his most ingenious device of a rapidly rotating mirror, Wheatstone had proved that electricity required time to pa.s.s through a wire, the current reaching the middle of the wire later than its two ends. 'If,' says Faraday, 'the two ends of the wire in Professor Wheatstone's experiments were immediately connected with two large insulated metallic surfaces exposed to the air, so that the primary act of induction, after making the contact for discharge, might be in part removed from the internal portion of the wire at the first instance, and disposed for the moment on its surface jointly with the air and surrounding conductors, then I venture to antic.i.p.ate that the middle spark would be more r.e.t.a.r.ded than before. And if those two plates were the inner and outer coatings of a large jar or Leyden battery, then the r.e.t.a.r.dation of the spark would be much greater.' This was only a prediction, for the experiment was not made.[2] Sixteen years subsequently, however, the proper conditions came into play, and Faraday was able to show that the observations of Werner Siemens, and Latimer Clark, on subterraneous and submarine wires were ill.u.s.trations, on a grand scale, of the principle which he had enunciated in 1838. The wires and the surrounding water act as a Leyden jar, and the r.e.t.a.r.dation of the current predicted by Faraday manifests itself in every message sent by such cables.
The meaning of Faraday in these memoirs on Induction and Conduction is, as I have said, by no means always clear; and the difficulty will be most felt by those who are best trained in ordinary theoretic conceptions. He does not know the reader's needs, and he therefore does not meet them. For instance he speaks over and over again of the impossibility of charging a body with one electricity, though the impossibility is by no means evident. The key to the difficulty is this.
He looks upon every insulated conductor as the inner coating of a Leyden jar. An insulated sphere in the middle of a room is to his mind such a coating; the walls are the outer coating, while the air between both is the insulator, across which the charge acts by induction. Without this reaction of the walls upon the sphere you could no more, according to Faraday, charge it with electricity than you could charge a Leyden jar, if its outer coating were removed. Distance with him is immaterial. His strength as a generalizer enables him to dissolve the idea of magnitude; and if you abolish the walls of the room--even the earth itself--he would make the sun and planets the outer coating of his jar. I dare not contend that Faraday in these memoirs made all his theoretic positions good. But a pure vein of philosophy runs through these writings; while his experiments and reasonings on the forms and phenomena of electrical discharge are of imperishable importance.
Footnotes to Chapter 8
[1] Newton's third letter to Bentley.
[2] Had Sir Charles Wheatstone been induced to resume his measurements, varying the substances through which, and the conditions under which, the current is propagated, he might have rendered great service to science, both theoretic and experimental.
Chapter 9.
Rest needed--visit to Switzerland.
The last of these memoirs was dated from the Royal Inst.i.tution in June, 1838. It concludes the first volume of his 'Experimental Researches on Electricity.' In 1840, as already stated, he made his final a.s.sault on the Contact Theory, from which it never recovered.[1] He was now feeling the effects of the mental strain to which he had been subjected for so many years. During these years he repeatedly broke down. His wife alone witnessed the extent of his prostration, and to her loving care we, and the world, are indebted for the enjoyment of his presence here so long.
He found occasional relief in a theatre. He frequently quitted London and went to Brighton and elsewhere, always choosing a situation which commanded a view of the sea, or of some other pleasant horizon, where he could sit and gaze and feel the gradual revival of the faith that
'Nature never did betray The heart that loved her.'
But very often for some days after his removal to the country, he would be unable to do more than sit at a window and look out upon the sea and sky.
In 1841, his state became more serious than it had ever been before. A published letter to Mr. Richard Taylor, dated March 11, 1843, contains an allusion to his previous condition. 'You are aware,' he says, 'that considerations regarding health have prevented me from working or reading on science for the last two years.' This, at one period or another of their lives, seems to be the fate of most great investigators. They do not know the limits of their const.i.tutional strength until they have transgressed them. It is, perhaps, right that they should transgress them, in order to ascertain where they lie.
Faraday, however, though he went far towards it, did not push his transgression beyond his power of rest.i.tution. In 1841 Mrs. Faraday and he went to Switzerland, under the affectionate charge of her brother, Mr. George Barnard, the artist. This time of suffering throws fresh light upon his character. I have said that sweetness and gentleness were not its only const.i.tuents; that he was also fiery and strong. At the time now referred to, his fire was low and his strength distilled away; but the residue of his life was neither irritability nor discontent. He was unfit to mingle in society, for conversation was a pain to him; but let us observe the great Man-child when alone. He is at the village of Interlaken, enjoying Jungfrau sunsets, and at times watching the Swiss nailers making their nails. He keeps a little journal, in which he describes the process of nailmaking, and incidentally throws a luminous beam upon himself.
'August 2, 1841.--Clout nailmaking goes on here rather considerably, and is a very neat and pretty operation to observe. I love a smith's shop and anything relating to smithery. My father was a smith.'
From Interlaken he went to the Falls of the Giessbach, on the pleasant lake of Brientz. And here we have him watching the shoot of the cataract down its series of precipices. It is shattered into foam at the base of each, and tossed by its own recoil as water-dust through the air. The sun is at his back, s.h.i.+ning on the drifting spray, and he thus describes and muses on what he sees:--
'August 12, 1841.--To-day every fall was foaming from the abundance of water, and the current of wind brought down by it was in some places too strong to stand against. The sun shone brightly, and the rainbows seen from various points were very beautiful. One at the bottom of a fine but furious fall was very pleasant,--there it remained motionless, whilst the gusts and clouds of spray swept furiously across its place and were dashed against the rock. It looked like a spirit strong in faith and steadfast in the midst of the storm of pa.s.sions sweeping across it, and though it might fade and revive, still it held on to the rock as in hope and giving hope. And the very drops, which in the whirlwind of their fury seemed as if they would carry all away, were made to revive it and give it greater beauty.'
Footnote to Chapter 9
[1] See note, p. 77.
Chapter 10.
Magnetization of light.
But we must quit the man and go on to the discoverer: we shall return for a brief s.p.a.ce to his company by-and-by. Carry your thoughts back to his last experiments, and see him endeavouring to prove that induction is due to the action of contiguous particles. He knew that polarized light was a most subtle and delicate investigator of molecular condition. He used it in 1834 in exploring his electrolytes, and he tried it in 1838 upon his dielectrics. At that time he coated two opposite faces of a gla.s.s cube with tinfoil, connected one coating with his powerful electric machine and the other with the earth, and examined by polarized light the condition of the gla.s.s when thus subjected to strong electric influence. He failed to obtain any effect; still he was persuaded an action existed, and required only suitable means to call it forth.
After his return from Switzerland he was beset by these thoughts; they were more inspired than logical: but he resorted to magnets and proved his inspiration true. His dislike of 'doubtful knowledge' and his efforts to liberate his mind from the thraldom of hypotheses have been already referred to. Still this rebel against theory was incessantly theorising himself. His princ.i.p.al researches are all connected by an undercurrent of speculation. Theoretic ideas were the very sap of his intellect--the source from which all his strength as an experimenter was derived. While once sauntering with him through the Crystal Palace, at Sydenham, I asked him what directed his attention to the magnetization of light. It was his theoretic notions. He had certain views regarding the unity and convertibility of natural forces; certain ideas regarding the vibrations of light and their relations to the lines of magnetic force; these views and ideas drove him to investigation. And so it must always be: the great experimentalist must ever be the habitual theorist, whether or not he gives to his theories formal enunciation.
Faraday, you have been informed, endeavoured to improve the manufacture of gla.s.s for optical purposes. But though he produced a heavy gla.s.s of great refractive power, its value to optics did not repay him for the pains and labour bestowed on it. Now, however, we reach a result established by means of this same heavy gla.s.s, which made ample amends for all.
In November, 1845, he announced his discovery of the 'Magnetization of Light and the Illumination of the Lines of Magnetic Force.' This t.i.tle provoked comment at the time, and caused misapprehension. He therefore added an explanatory note; but the note left his meaning as entangled as before. In fact Faraday had notions regarding the magnetization of light which were peculiar to himself, and untranslatable into the scientific language of the time. Probably no other philosopher of his day would have employed the phrases just quoted as appropriate to the discovery announced in 1845. But Faraday was more than a philosopher; he was a prophet, and often wrought by an inspiration to be understood by sympathy alone. The prophetic element in his character occasionally coloured, and even injured, the utterance of the man of science; but subtracting that element, though you might have conferred on him intellectual symmetry, you would have destroyed his motive force.
But let us pa.s.s from the label of this casket to the jewel it contains. 'I have long,' he says, 'held an opinion, almost amounting to conviction, in common, I believe, with many other lovers of natural knowledge, that the various forms under which the forces of matter are made manifest have one common origin; in other words, are so directly related and mutually dependent, that they are convertible, as it were, into one another, and possess equivalents of power in their action....
This strong persuasion,' he adds, 'extended to the powers of light.'
And then he examines the action of magnets upon light. From conversation with him and Anderson, I should infer that the labour preceding this discovery was very great. The world knows little of the toil of the discoverer. It sees the climber jubilant on the mountain top, but does not know the labour expended in reaching it. Probably hundreds of experiments had been made on transparent crystals before he thought of testing his heavy gla.s.s. Here is his own clear and simple description of the result of his first experiment with this substance:--'A piece of this gla.s.s, about two inches square, and 0.5 of an inch thick, having flat and polished edges, was placed as a diamagnetic[1] between the poles (not as yet magnetized by the electric current), so that the polarized ray should pa.s.s through its length; the gla.s.s acted as air, water, or any other transparent substance would do; and if the eye-piece were previously turned into such a position that the polarized ray was extinguished, or rather the image produced by it rendered invisible, then the introduction of the gla.s.s made no alteration in this respect.
In this state of circ.u.mstances, the force of the electro-magnet was developed by sending an electric current through its coils, and immediately the image of the lamp-flame became visible and continued so as long as the arrangement continued magnetic. On stopping the electric current, and so causing the magnetic force to cease, the light instantly disappeared. These phenomena could be renewed at pleasure, at any instant of time, and upon any occasion, showing a perfect dependence of cause and effect.'
In a beam of ordinary light the particles of the luminiferous ether vibrate in all directions perpendicular to the line of progression; by the act of polarization, performed here by Faraday, all oscillations but those parallel to a certain plane are eliminated. When the plane of vibration of the polarizer coincides with that of the a.n.a.lyzer, a portion of the beam pa.s.ses through both; but when these two planes are at right angles to each other, the beam is extinguished. If by any means, while the polarizer and a.n.a.lyzer remain thus crossed, the plane of vibration of the polarized beam between them could be changed, then the light would be, in part at least, transmitted. In Faraday's experiment this was accomplished. His magnet turned the plane of polarization of the beam through a certain angle, and thus enabled it to get through the a.n.a.lyzer; so that 'the magnetization of light and the illumination of the magnetic lines of force' becomes, when expressed in the language of modern theory, the rotation of the plane of polarization.
To him, as to all true philosophers, the main value of a fact was its position and suggestiveness in the general sequence of scientific truth.
Hence, having established the existence of a phenomenon, his habit was to look at it from all possible points of view, and to develop its relations.h.i.+p to other phenomena. He proved that the direction of the rotation depends upon the polarity of his magnet; being reversed when the magnetic poles are reversed. He showed that when a polarized ray pa.s.sed through his heavy gla.s.s in a direction parallel to the magnetic lines of force, the rotation is a maximum, and that when the direction of the ray is at right angles to the lines of force, there is no rotation at all. He also proved that the amount of the rotation is proportional to the length of the diamagnetic through which the ray pa.s.ses. He operated with liquids and solutions. Of aqueous solutions he tried 150 and more, and found the power in all of them. He then examined gases; but here all his efforts to produce any sensible action upon the polarized beam were ineffectual. He then pa.s.sed from magnets to currents, enclosing bars of heavy gla.s.s, and tubes containing liquids and aqueous solutions within an electro-magnetic helix. A current sent through the helix caused the plane of polarization to rotate, and always in the direction of the current. The rotation was reversed when the current was reversed. In the case of magnets, he observed a gradual, though quick, ascent of the transmitted beam from a state of darkness to its maximum brilliancy, when the magnet was excited. In the case of currents, the beam attained at once its maximum. This he showed to be due to the time required by the iron of the electro-magnet to a.s.sume its full magnetic power, which time vanishes when a current, without iron, is employed. 'In this experiment,' he says, 'we may, I think, justly say that a ray of light is electrified, and the electric forces illuminated.' In the helix, as with the magnets, he submitted air to magnetic influence 'carefully and anxiously,' but could not discover any trace of action on the polarized ray.
Many substances possess the power of turning the plane of polarization without the intervention of magnetism. Oil of turpentine and quartz are examples; but Faraday showed that, while in one direction, that is, across the lines of magnetic force, his rotation is zero, augmenting gradually from this until it attains its maximum, when the direction of the ray is parallel to the lines of force; in the oil of turpentine the rotation is independent of the direction of the ray. But he showed that a still more profound distinction exists between the magnetic rotation and the natural one. I will try to explain how. Suppose a tube with gla.s.s ends containing oil of turpentine to be placed north and south.
Fixing the eye at the south end of the tube, let a polarized beam be sent through it from the north. To the observer in this position the rotation of the plane of polarization, by the turpentine, is right-handed. Let the eye be placed at the north end of the tube, and a beam be sent through it from the south; the rotation is still right-handed. Not so, however, when a bar of heavy gla.s.s is subjected to the action of an electric current. In this case if, in the first position of the eye, the rotation be right-handed, in the second position it is left-handed. These considerations make it manifest that if a polarized beam, after having pa.s.sed through the oil of turpentine in its natural state, could by any means be reflected back through the liquid, the rotation impressed upon the direct beam would be exactly neutralized by that impressed upon the reflected one. Not so with the induced magnetic effect. Here it is manifest that the rotation would be doubled by the act of reflection. Hence Faraday concludes that the particles of the oil of turpentine which rotate by virtue of their natural force, and those which rotate in virtue of the induced force, cannot be in the same condition. The same remark applies to all bodies which possess a natural power of rotating the plane of polarization.
And then he proceeded with exquisite skill and insight to take advantage of this conclusion. He silvered the ends of his piece of heavy gla.s.s, leaving, however, a narrow portion parallel to two edges diagonally opposed to each other unsilvered. He then sent his beam through this uncovered portion, and by suitably inclining his gla.s.s caused the beam within it to reach his eye first direct, and then after two, four, and six reflections. These corresponded to the pa.s.sage of the ray once, three times, five times, and seven times through the gla.s.s. He thus established with numerical accuracy the exact proportionality of the rotation to the distance traversed by the polarized beam. Thus in one series of experiments where the rotation required by the direct beam was 12degrees, that acquired by three pa.s.sages through the gla.s.s was 36degrees, while that acquired by five pa.s.sages was 60degrees. But even when this method of magnifying was applied, he failed with various solid substances to obtain any effect; and in the case of air, though he employed to the utmost the power which these repeated reflections placed in his hands, he failed to produce the slightest sensible rotation.
These failures of Faraday to obtain the effect with gases seem to indicate the true seat of the phenomenon. The luminiferous ether surrounds and is influenced by the ultimate particles of matter. The symmetry of the one involves that of the other. Thus, if the molecules of a crystal be perfectly symmetrical round any line through the crystal, we may safely conclude that a ray will pa.s.s along this line as through ordinary gla.s.s. It will not be doubly refracted. From the symmetry of the liquid figures, known to be produced in the planes of freezing, when radiant heat is sent through ice, we may safely infer symmetry of aggregation, and hence conclude that the line perpendicular to the planes of freezing is a line of no double refraction; that it is, in fact, the optic axis of the crystal. The same remark applies to the line joining the opposite blunt angles of a crystal of Iceland spar.
The arrangement of the molecules round this line being symmetrical, the condition of the ether depending upon these molecules shares their symmetry; and there is, therefore, no reason why the wavelength should alter with the alteration of the azimuth round this line. Annealed gla.s.s has its molecules symmetrically arranged round every line that can be drawn through it; hence it is not doubly refractive. But let the substance be either squeezed or strained in one direction, the molecular symmetry, and with it the symmetry of the ether, is immediately destroyed and the gla.s.s becomes doubly refractive. Unequal heating produces the same effect. Thus mechanical strains reveal themselves by optical effects; and there is little doubt that in Faraday's experiment it is the magnetic strain that produces the rotation of the plane of polarization.[2]
Footnotes to Chapter 10
[1] 'By a diamagnetic,' says Faraday, 'I mean a body through which lines of magnetic force are pa.s.sing, and which does not by their action a.s.sume the usual magnetic state of iron or loadstone.' Faraday subsequently used this term in a different sense from that here given, as will immediately appear.
[2] The power of double refraction conferred on the centre of a gla.s.s rod, when it is caused to sound the fundamental note due to its longitudinal vibration, and the absence of the same power in the case of vibrating air (enclosed in a gla.s.s organ-pipe), seems to be a.n.a.logous to the presence and absence of Faraday's effect in the same two substances.
Faraday never, to my knowledge, attempted to give, even in conversation, a picture of the molecular condition of his heavy gla.s.s when subjected to magnetic influence. In a mathematical investigation of the subject, published in the Proceedings of the Royal Society for 1856, Sir William Thomson arrives at the conclusion that the 'diamagnetic' is in a state of molecular rotation.
Faraday as a Discoverer Part 4
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