Essays: Scientific, Political, & Speculative Part 6
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From the mechanical arrangements of the Solar System, turn we now to its physical characters; and, first, let us consider the inferences deducible from relative specific gravities.
The fact that, speaking generally, the denser planets are the nearer to the Sun, has been by some considered as adding another to the many indications of nebular origin. Legitimately a.s.suming that the outermost parts of a rotating nebulous spheroid, in its earlier stages of concentration, must be comparatively rare; and that the increasing density which the whole ma.s.s acquires as it contracts, must hold of the outermost parts as well as the rest; it is argued that the rings successively detached will be more and more dense, and will form planets of higher and higher specific gravities. But pa.s.sing over other objections, this explanation is quite inadequate to account for the facts. Using the Earth as a standard of comparison, the relative densities run thus:--
Neptune. Ura.n.u.s. Saturn. Jupiter. Mars. Earth. Venus. Mercury. Sun.
017 025 011 023 045 100 092 126 025
Two insurmountable objections are presented by this series. The first is, that the progression is but a broken one. Neptune is denser than Saturn, which, by the hypothesis, it ought not to be. Ura.n.u.s is denser than Jupiter, which it ought not to be. Ura.n.u.s is denser than Saturn, and the Earth is denser than Venus--facts which not only give no countenance to, but directly contradict, the alleged explanation. The second objection, still more manifestly fatal, is the low specific gravity of the Sun. If, when the matter of the Sun filled the orbit of Mercury, its state of aggregation was such that the detached ring formed a planet having a specific gravity equal to that of iron; then the Sun itself, now that it has concentrated, should have a specific gravity much greater than that of iron; whereas its specific gravity is only half as much again as that of water. Instead of being far denser than the nearest planet, it is but one-fifth as dense.
While these anomalies render untenable the position that the relative specific gravities of the planets are direct indications of nebular condensation; it by no means follows that they negative it. Several causes may be a.s.signed for these unlikenesses:--1. Differences among the planets in respect of the elementary substances composing them; or in the proportions of such elementary substances, if they contain the same kinds. 2. Differences among them in respect of the quant.i.ties of matter they contain; for, other things equal, the mutual gravitation of molecules will make a larger ma.s.s denser than a smaller. 3. Differences of temperatures; for, other things equal, those having higher temperatures will have lower specific gravities. 4. Differences of physical states, as being gaseous, liquid, or solid; or, otherwise, differences in the relative amounts of the solid, liquid, and gaseous matter they contain.
It is quite possible, and we may indeed say probable, that all these causes come into play, and that they take various shares in the production of the several results. But difficulties stand in the way of definite conclusions. Nevertheless, if we revert to the hypothesis of nebular genesis, we are furnished with partial explanations if nothing more.
In the cooling of celestial bodies several factors are concerned. The first and simplest is the one ill.u.s.trated at every fire-side by the rapid blackening of little cinders which fall into the ashes, in contrast with the long-continued redness of big lumps. This factor is the relation between increase of surface and increase of content: surfaces, in similar bodies, increasing as the squares of the dimensions while contents increase as their cubes. Hence, on comparing the Earth with Jupiter, whose diameter is about eleven times that of the Earth, it results that while his surface is 125 times as great, his content is 1390 times as great. Now even (supposing we a.s.sume like temperatures and like densities) if the only effect were that through a given area of surface eleven times more matter had to be cooled in the one case than in the other, there would be a vast difference between the times occupied in concentration. But, in virtue of a second factor, the difference would be much greater than that consequent on these geometrical relations. The escape of heat from a cooling ma.s.s is effected by conduction, or by convection, or by both. In a solid it is wholly by conduction; in a liquid or gas the chief part is played by convection--by circulating currents which continually transpose the hotter and cooler parts. Now in fluid spheroids--gaseous, or liquid, or mixed--increasing size entails an increasing obstacle to cooling, consequent on the increasing distances to be travelled by the circulating currents. Of course the relation is not a simple one: the velocities of the currents will be unlike. It is manifest, however, that in a sphere of eleven times the diameter, the transit of matter from centre to surface and back from surface to centre, will take a much longer time; even if its movement is unrestrained. But its movement is, in such cases as we are considering, greatly restrained. In a rotating spheroid there come into play r.e.t.a.r.ding forces augmenting with the velocity of rotation. In such a spheroid the respective portions of matter (supposing them equal in their angular velocities round the axis, which they will tend more and more to become as the density increases), must vary in their absolute velocities according to their distances from the axis; and each portion cannot have its distance from the axis changed by circulating currents, which it must continually be, without loss or gain in its quant.i.ty of motion: through the medium of fluid friction, force must be expended, now in increasing its motion and now in r.e.t.a.r.ding its motion. Hence, when the larger spheroid has also a higher velocity of rotation, the relative slowness of the circulating currents, and the consequent r.e.t.a.r.dation of cooling, must be much greater than is implied by the extra distances to be travelled.
And now observe the correspondence between inference and fact. In the first place, if we compare the group of the great planets, Jupiter, Saturn, and Ura.n.u.s, with the group of the small planets, Mars, Earth, Venus, and Mercury, we see that low density goes along with great size and great velocity of rotation, and that high density goes along with small size and small velocity of rotation. In the second place, we are shown this relation still more clearly if we compare the extreme instances--Saturn and Mercury. The special contrast of these two, like the general contrast of the groups, points to the truth that low density, like the satellite-forming tendency, is a.s.sociated with the ratio borne by centrifugal force to gravity; for in the case of Saturn with his many satellites and least density, centrifugal force at the equator is nearly 1/6th of gravity, whereas in Mercury with no satellite and greatest density centrifugal force is but 1/360th of gravity.
There are, however, certain factors which, working in an opposite way, qualify and complicate these effects. Other things equal, mutual gravitation among the parts of a large ma.s.s will cause a greater evolution of heat than is similarly caused in a small ma.s.s; and the resulting difference of temperature will tend to produce more rapid dissipation of heat. To this must be added the greater velocity of the circulating currents which the intenser forces at work in larger spheroids will produce--a contrast made still greater by the relatively smaller r.e.t.a.r.dation by friction to which the more voluminous currents are exposed. In these causes, joined with causes previously indicated, we may recognize a probable explanation of the otherwise anomalous fact that the Sun, though having a thousand times the ma.s.s of Jupiter, has yet reached as advanced a stage of concentration. For the force of gravity in the Sun, which at his surface is some ten times that at the surface of Jupiter, must expose his central parts to a pressure relatively very intense; producing, during contraction, a relatively rapid genesis of heat. And it is further to be remarked that, though the circulating currents in the Sun have far greater distances to travel, yet since his rotation is relatively so slow that the angular velocity of his substance is but about one-sixtieth of that of Jupiter's substance, the resulting obstacle to circulating currents is relatively small, and the escape of heat far less r.e.t.a.r.ded. Here, too, we may note that in the co-operation of these factors, there seems a reason for the greater concentration reached by Jupiter than by Saturn, though Saturn is the elder as well as the smaller of the two; for at the same time that the gravitative force in Jupiter is more than twice as great as in Saturn, his velocity of rotation is very little greater, so that the opposition of the centrifugal force to the centripetal is not much more than half.
But now, not judging more than roughly of the effects of these several factors, co-operating in various ways and degrees, some to aid concentration and others to resist it, it is sufficiently manifest that, other things equal, the larger nebulous spheroids, longer in losing their heat, will more slowly reach high specific gravities; and that where the contrasts in size are so immense as those between the greater and the smaller planets, the smaller may have reached relatively high specific gravities when the greater have reached but relatively low ones. Further, it appears that such qualification of the process as results from the more rapid genesis of heat in the larger ma.s.ses, will be countervailed where high velocity of rotation greatly impedes the circulating currents. Thus interpreted then, the various specific gravities of the planets may be held to furnish further evidences supporting the Nebular Hypothesis.
Increase of density and escape of heat are correlated phenomena, and hence in the foregoing section, treating of the respective densities of the celestial bodies in connexion with nebular condensation, much has been said and implied respecting the accompanying genesis and dissipation of heat. Quite apart, however, from the foregoing arguments and inferences, there is to be noted the fact that in the present temperatures of the celestial bodies at large we find additional supports to the hypothesis; and these, too, of the most substantial character. For if, as is implied above, heat must inevitably be generated by the aggregation of diffused matter, we ought to find in all the heavenly bodies, either present high temperatures or marks of past high temperatures. This we do, in the places and in the degrees which the hypothesis requires.
Observations showing that as we descend below the Earth's surface there is a progressive increase of heat, joined with the conspicuous evidence furnished by volcanoes, necessitate the conclusion that the temperature is very high at great depths. Whether, as some believe, the interior of the Earth is still molten, or whether, as Sir William Thomson contends, it must be solid; there is agreement in the inference that its heat is intense. And it has been further shown that the rate at which the temperature increases on descending below the surface, is such as would be found in a ma.s.s which had been cooling for an indefinite period. The Moon, too, shows us, by its corrugations and its conspicuous extinct volcanoes, that in it there has been a process of refrigeration and contraction, like that which has gone on in the Earth. There is no teleological explanation of these facts. The frequent destructions of life by earthquakes and volcanoes, imply, rather, that it would have been better had the Earth been created with a low internal temperature.
But if we contemplate the facts in connexion with the Nebular Hypothesis, we see that this still-continued high internal heat is one of its corollaries. The Earth must have pa.s.sed through the gaseous and the molten conditions before it became solid, and must for an almost infinite period by its internal heat continue to bear evidence of this origin.
The group of giant planets furnishes remarkable evidence. The _a priori_ inference drawn above, that great size joined with relatively high ratio of centrifugal force to gravity must greatly r.e.t.a.r.d aggregation, and must thus, by checking the genesis and dissipation of heat, make the process of cooling a slow one, has of late years received verifications from inferences drawn _a posteriori_; so that now the current conclusion among astronomers is that in physical condition the great planets are in stages midway between that of the Earth and that of the Sun. The fact that the centre of Jupiter's disc is twice or thrice as bright as his periphery, joined with the facts that he seems to radiate more light than is accounted for by reflection of the Sun's rays, and that his spectrum shows the "red-star line", are taken as evidences of luminosity; while the immense and rapid perturbations in his atmosphere, far greater than could be caused by heat received from the Sun, as well as the formation of spots a.n.a.logous to those of the Sun, which also, like those of the Sun, show a higher rate of rotation near the equator than further from it, are held to imply high internal temperature. Thus in Jupiter, as also in Saturn, we find states which, not admitting of any teleological explanations (for they manifestly exclude the possibility of life), admit of explanations derived from the Nebular Hypothesis.
But the argument from temperature does not end here. There remains to be noticed a more conspicuous and still more significant fact. If the Solar System was produced by the concentration of diffused matter, which evolved heat while gravitating into its present dense form; then there is an obvious implication. Other things equal, the latest-formed ma.s.s will be the latest in cooling--will, for an almost infinite time, possess a greater heat than the earlier-formed ones. Other things equal, the largest ma.s.s will, because of its superior aggregative force, become hotter than the others, and radiate more intensely. Other things equal, the largest ma.s.s, notwithstanding the higher temperature it reaches, will, in consequence of its relatively small surface, be the slowest in losing its evolved heat. And hence, if there is one ma.s.s which was not only formed after the rest, but exceeds them enormously in size, it follows that this one will reach an intensity of incandescence far beyond that reached by the rest; and will continue in a state of intense incandescence long after the rest have cooled. Such a ma.s.s we have in the Sun. It is a corollary from the Nebular Hypothesis, that the matter forming the Sun a.s.sumed its present integrated shape at a period much more recent than that at which the planets became definite bodies. The quant.i.ty of matter contained in the Sun is nearly five million times that contained in the smallest planet, and above a thousand times that contained in the largest. And while, from the enormous gravitative force of his parts to their common centre, the evolution of heat has been intense, the facilities of radiation have been relatively small. Hence the still-continued high temperature. Just that condition of the central body which is a necessary inference from the Nebular Hypothesis, we find actually existing in the Sun.
[The paragraph which here follows, though it contains some questionable propositions, I reproduce just as it stood when first published in 1858, for reasons which will presently be apparent.]
It may be well to consider more closely, what is the probable condition of the Sun's surface. Round the globe of incandescent molten substances, thus conceived to form the visible body of the Sun [which in conformity with the argument in a previous section, now transferred to the Addenda, was inferred to be hollow and filled with gaseous matter at high tension] there is known to exist a voluminous atmosphere: the inferior brilliancy of the Sun's border, and the appearances during a total eclipse, alike show this. What now must be the const.i.tution of this atmosphere? At a temperature approaching a thousand times that of molten iron, which is the calculated temperature of the solar surface, very many, if not all, of the substances we know as solid, would become gaseous; and though the Sun's enormous attractive force must be a powerful check on this tendency to a.s.sume the form of vapour, yet it cannot be questioned that if the body of the Sun consists of molten substances, some of them must be constantly undergoing evaporation. That the dense gases thus continually being generated will form the entire ma.s.s of the solar atmosphere, is not probable. If anything is to be inferred, either from the Nebular Hypothesis, or from the a.n.a.logies supplied by the planets, it must be concluded that the outermost part of the solar atmosphere consists of what are called permanent gases--gases that are not condensible into fluid even at low temperatures. If we consider what must have been the state of things here, when the surface of the Earth was molten, we shall see that round the still molten surface of the Sun, there probably exists a stratum of dense aeriform matter, made up of sublimed metals and metallic compounds, and above this a stratum of comparatively rare medium a.n.a.logous to air. What now will happen with these two strata? Did they both consist of permanent gases, they could not remain separate: according to a well-known law, they would eventually form a h.o.m.ogeneous mixture. But this will by no means happen when the lower stratum consists of matters that are gaseous only at excessively high temperatures. Given off from a molten surface, ascending, expanding, and cooling, these will presently reach a limit of elevation above which they cannot exist as vapour, but must condense and precipitate. Meanwhile the upper stratum, habitually charged with its quantum of these denser matters, as our air with its quantum of water, and ready to deposit them on any depression of temperature, must be habitually unable to take up any more of the lower stratum; and therefore this lower stratum will remain quite distinct from it.[20]
Considered in their _ensemble_, the several groups of evidences a.s.signed amount almost to proof. We have seen that, when critically examined, the speculations of late years current respecting the nature of the nebulae, commit their promulgators to sundry absurdities; while, on the other hand, we see that the various appearances these nebulae present, are explicable as different stages in the precipitation and aggregation of diffused matter. We find that the immense majority of comets (_i.e._ omitting the periodic ones), by their physical const.i.tution, their immensely-extended and variously-directed paths, the distribution of those paths, and their manifest structural relation to the Solar System, bear testimony to the past existence of that system in a nebulous form.
Not only do those obvious peculiarities in the motions of the planets which first suggested the Nebular Hypothesis, supply proofs of it, but on closer examination we discover, in the slightly-diverging inclinations of their orbits, in their various rates of rotation, and their differently-directed axes of rotation, that the planets yield us yet further testimony; while the satellites, by sundry traits, and especially by their occurrence in greater or less abundance where the hypothesis implies greater or less abundance, confirm this testimony. By tracing out the process of planetary condensation, we are led to conclusions respecting the physical states of planets which explain their anomalous specific gravities. Once more, it turns out that what is inferable from the Nebular Hypothesis respecting the temperatures of celestial bodies, is just what observation establishes; and that both the absolute and the relative temperatures of the Sun and planets are thus accounted for. When we contemplate these various evidences in their totality--when we observe that, by the Nebular Hypothesis, the leading phenomena of the Solar System, and the heavens in general, are explicable; and when, on the other hand, we consider that the current cosmogony is not only without a single fact to stand on, but is at variance with all our positive knowledge of Nature, we see that the proof becomes overwhelming.
It remains only to point out that while the genesis of the Solar System, and of countless other systems like it, is thus rendered comprehensible, the ultimate mystery continues as great as ever. The problem of existence is not solved: it is simply removed further back. The Nebular Hypothesis throws no light on the origin of diffused matter; and diffused matter as much needs accounting for as concrete matter. The genesis of an atom is not easier to conceive than the genesis of a planet. Nay, indeed, so far from making the Universe less a mystery than before, it makes it a greater mystery. Creation by manufacture is a much lower thing than creation by evolution. A man can put together a machine; but he cannot make a machine develop itself. That our harmonious universe once existed potentially as formless diffused matter, and has slowly grown into its present organized state, is a far more astonis.h.i.+ng fact than would have been its formation after the artificial method vulgarly supposed. Those who hold it legitimate to argue from phenomena to noumena, may rightly contend that the Nebular Hypothesis implies a First Cause as much transcending "the mechanical G.o.d of Paley," as this does the fetish of the savage.
FOOTNOTES:
[Footnote 11: _Cosmos._ (Seventh Edition.) Vol. i. pp. 79, 80.]
[Footnote 12: Since the publication of this essay the late Mr. R. A.
Proctor has given various further reasons for the conclusion that the nebulae belong to our own sidereal system. The opposite conclusion, contested throughout the foregoing section, has now been tacitly abandoned.]
[Footnote 13: Any objection made to the extreme tenuity this involves, is met by the calculation of Newton, who proved that were a spherical inch of air removed four thousand miles from the Earth, it would expand into a sphere more than filling the orbit of Saturn.]
[Footnote 14: A reference may fitly be made here to a reason given by Mons. Babinet for rejection of the Nebular Hypothesis. He has calculated that taking the existing Sun, with its observed angular velocity, its substance, if expanded so as to fill the orbit of Neptune, would have nothing approaching the angular velocity which the time of revolution of that planet implies. The a.s.sumption he makes is inadmissible. He supposes that all parts of the nebulous spheroid when it filled Neptune's...o...b..t, had the same angular velocities. But the process of nebular condensation as indicated above, implies that the remoter flocculi of nebulous matter, later in reaching the central ma.s.s, and forming its peripheral portions, will acquire, during their longer journeys towards it, greater velocities. An inspection of one of the spiral nebulae, as 51st or 99th Messier, at once shows that the outlying portions when they reach the nucleus, will form an equatorial belt moving round the common centre more rapidly than the rest. Thus the central parts will have small angular velocities, while there will be increasing angular velocities of parts increasingly remote from the centre. And while the density of the spheroid continues small, fluid friction will scarcely at all change these differences.
A like criticism may, I think, be pa.s.sed on an opinion expressed by Prof. Newcomb. He says:--"When the contraction [of the nebulous spheroid] had gone so far that the centrifugal and attracting forces nearly balanced each other at the outer equatorial limit of the ma.s.s, the result would have been that contraction in the direction of the equator would cease entirely, and be confined to the polar regions, each particle dropping, not towards the sun, but towards the plane of the solar equator. Thus, we should have a constant flattening of the spheroidal atmosphere until it was reduced to a thin flat disk. This disk might then separate itself into rings, which would form planets in much the same way that Laplace supposed. But there would probably be no marked difference in the age of the planets." (_Popular Astronomy_, p. 512.) Now this conclusion a.s.sumes, like that of M. Babinet, that all parts of the nebulous spheroid had equal angular velocities. If, as above contended, it is inferable from the process by which a nebulous spheroid was formed, that its outer portions revolved with greater angular velocities than its inner; then the inference which Prof.
Newcomb draws is not necessitated.]
[Footnote 15: It is true that since this essay was written reasons have been given for concluding that comets consist of swarms of meteors enveloped in aeriform matter. Very possibly this is the const.i.tution of the periodic comets which, approximating their orbits to the plane of the Solar System, form established parts of the System, and which, as will be hereafter indicated, have probably a quite different origin.]
[Footnote 16: Though this rule fails at the periphery of the Solar System, yet it fails only where the axis of rotation, instead of being almost perpendicular to the orbit-plane, is very little inclined to it; and where, therefore, the forces tending to produce the congruity of motions were but little operative.]
[Footnote 17: It is true that, as expressed by him, these propositions of Laplace are not all beyond dispute. An astronomer of the highest authority, who has favoured me with some criticisms on this essay, alleges that instead of a nebulous ring rupturing at one point, and collapsing into a single ma.s.s, "all probability would be in favour of its breaking up into many ma.s.ses." This alternative result certainly seems the more likely. But granting that a nebulous ring would break up into many ma.s.ses, it may still be contended that, since the chances are infinity to one against these being of equal sizes _and_ equidistant, they could not remain evenly distributed round their orbit. This annular chain of gaseous ma.s.ses would break up into groups of ma.s.ses; these groups would eventually aggregate into larger groups; and the final result would be the formation of a single ma.s.s. I have put the question to an astronomer scarcely second in authority to the one above referred to, and he agrees that this would probably be the process.]
[Footnote 18: The comparative statement here given differs, slightly in most cases and in one case largely, from the statement included in this essay as originally published in 1858. As then given the table ran thus:--
Mercury. 1/362 Venus. 1/282 Earth. 1/289 1 Satellite.
Mars. 1/326 Jupiter. 1/14 4 Satellites.
Saturn. 1/62 8 Satellites, and three rings.
Ura.n.u.s. 1/9 4 (or 6 according to Herschel).
The calculations ending with these figures were made while the Sun's distance was still estimated at 95 millions of miles. Of course the reduction afterwards established in the estimated distance, entailing, as it did, changes in the factors which entered into the calculations, affected the results; and, though it was unlikely that the relations stated would be materially changed, it was needful to have the calculations made afresh. Mr. Lynn has been good enough to undertake this task, and the figures given in the text are his. In the case of Mars a large error in my calculation had arisen from accepting Arago's statement of his density (095), which proves to be something like double what it should be. Here a curious incident may be named. When, in 1877, it was discovered that Mars has two satellites, though, according to my hypothesis, it seemed that he should have none, my faith in it received a shock; and since that time I have occasionally considered whether the fact is in any way reconcilable with the hypothesis. But now the proof afforded by Mr. Lynn that my calculation contained a wrong factor, disposes of the difficulty--nay, changes the objection to a verification. It turns out that, according to the hypothesis, Mars _ought_ to have satellites; and, further, that he ought to have a number intermediate between 1 and 4.]
[Footnote 19: Since this paragraph was first published, the discovery that Mars has two satellites revolving round him in periods shorter than that of his rotation, has shown that the implication on which Laplace here insists is general only, and not absolute. Were it a necessary a.s.sumption that all parts of a concentrating nebulous spheroid revolve with the same angular velocities, the exception would appear an inexplicable one; but if, as suggested in a preceding section, it is inferable from the process of formation of a nebulous spheroid, that its outer strata will move round the general axis with higher angular velocities than the inner ones, there follows a possible interpretation.
Though, during the earlier stages of concentration, while the nebulous matter, and especially its peripheral portions, are very rare, the effects of fluid-friction will be too small to change greatly such differences of angular velocities as exist; yet, when concentration has reached its last stages, and the matter is pa.s.sing from the gaseous into the liquid and solid states, and when also the convection-currents have become common to the whole ma.s.s (which they probably at first are not), the angular velocity of the peripheral portion will gradually be a.s.similated to that of the interior; and it becomes comprehensible that in the case of Mars the peripheral portion, more and more dragged back by the internal ma.s.s, lost part of its velocity during the interval between the formation of the innermost satellite and the arrival at the final form.]
[Footnote 20: I was about to suppress part of the above paragraph, written before the science of solar physics had taken shape, because of certain physical difficulties which stand in the way of its argument, when, on looking into recent astronomical works, I found that the hypothesis it sets forth respecting the Sun's structure has kins.h.i.+ps to the several hypotheses since set forth by Zollner, Faye, and Young. I have therefore decided to let it stand as it originally did.
The contemplated partial suppression just named, was prompted by recognition of the truth that to effect mechanical stability the gaseous interior of the Sun must have a density at least equal to that of the molten sh.e.l.l (greater, indeed, at the centre); and this seems to imply a specific gravity higher than that which he possesses. It may, indeed, be that the unknown elements which spectrum a.n.a.lysis shows to exist in the Sun, are metals of very low specific gravities, and that, existing in large proportion with other of the lighter metals, they may form a molten sh.e.l.l not denser than is implied by the facts. But this can be regarded as nothing more than a possibility.
No need, however, has arisen for either relinquis.h.i.+ng or holding but loosely the a.s.sociated conclusions respecting the const.i.tution of the photosphere and its envelope. Widely speculative as seemed these suggested corollaries from the Nebular Hypothesis when set forth in 1858, and quite at variance with the beliefs then current, they proved to be not ill-founded. At the close of 1859, there came the discoveries of Kirchhoff, proving the existence of various metallic vapours in the Sun's atmosphere.]
ADDENDA.
Speculative as is much of the foregoing essay, it appears undesirable to include in it anything still more speculative. For this reason I have decided to set forth separately some views concerning the genesis of the so-called elements during nebular condensation, and concerning the accompanying physical effects. At the same time it has seemed best to detach from the essay some of the more debatable conclusions originally contained in it; so that its general argument may not be needlessly implicated with them. These new portions, together with the old portions which re-appear more or less modified, I here append in a series of notes.
NOTE I. For the belief that the so-called elements are compound there are both special reasons and general reasons. Among the special may be named the parallelism between allotropy and isomerism; the numerous lines in the spectrum of each element; and the cyclical law of Newlands and Mendeljeff. Of the more general reasons, which, as distinguished from these chemical or chemico-physical ones, may fitly be called cosmical, the following are the chief.
The general law of evolution, if it does not actually involve the conclusion that the so-called elements are compounds, yet affords _a priori_ ground for suspecting that they are such. The implication is that, while the matter composing the Solar System has progressed physically from that relatively-h.o.m.ogeneous state which it had as a nebula to that relatively-heterogeneous state presented by Sun, planets, and satellites, it has also progressed chemically, from the relatively-h.o.m.ogeneous state in which it was composed of one or a few types of matter, to that relatively-heterogeneous state in which it is composed of many types of matter very diverse in their properties. This deduction from the law which holds throughout the cosmos as now known to us, would have much weight even were it unsupported by induction; but a survey of chemical phenomena at large discloses several groups of inductive evidences supporting it.
The first is that since the cooling of the Earth reached an advanced stage, the components of its crust have been ever increasing in heterogeneity. When the so-called elements, originally existing in a dissociated state, united into oxides, acids, and other binary compounds, the total number of different substances was immensely augmented, the new substances were more complex than the old, and their properties were more varied. That is, the a.s.semblage became more heterogeneous in its kinds, in the composition of each kind, and in the range of chemical characters. When, at a later period, there arose salts and other compounds of similar degrees of complexity, there was again an increase of heterogeneity, alike in the aggregate and in its members.
And when, still later, matters cla.s.sed as organic became possible, the multiformity was yet further augmented in kindred ways. If, then, chemical evolution, so far as we can trace it, has been from the h.o.m.ogeneous to the heterogeneous, may we not fairly suppose that it has been so from the beginning? If, from late stages in the Earth's history, we run back, and find the lines of chemical evolution continually converging, until they bring us to bodies which we cannot decompose, may we not suspect that, could we run back these lines still further, we should come to still decreasing heterogeneity in the number and nature of the substances, until we reached something like h.o.m.ogeneity?
A parallel argument may be derived from consideration of the affinities and stabilities of chemical compounds. Beginning with the complex nitrogenous bodies out of which living things are formed, and which, in the history of the Earth, are the most modern, at the same time that they are the most heterogeneous, we see that the affinities and stabilities of these are extremely small. Their molecules do not enter bodily into union with those of other substances so as to form more complex compounds still, and their components often fail to hold together under ordinary conditions. A stage lower in degree of composition we come to the vast a.s.semblage of oxy-hydro-carbons, numbers of which show many and decided affinities, and are stable at common temperatures. Pa.s.sing to the inorganic group, we are shown by the salts &c. strong affinities between their components and unions which are, in many cases, not very easily broken. And then when we come to the oxides, acids, and other binary compounds, we see that in many cases the elements of which they are formed, when brought into the presence of one another under favourable conditions, unite with violence; and that many of their unions cannot be dissolved by heat alone. If, then, as we go back from the most modern and most complex substances to the most ancient and simplest substances, we see, on the average, a great increase in affinity and stability, it results that if the same law holds with the simplest substances known to us, the components of these, if they are compound, may be a.s.sumed to have united with affinities far more intense than any we have experience of, and to cling together with tenacities far exceeding the tenacities with which chemistry acquaints us. Hence the existence of a cla.s.s of substances which are undecomposable and therefore seem simple, appears to be an implication; and the corollary is that these were formed during early stages of terrestrial concentration, under conditions of heat and pressure which we cannot now parallel.
Essays: Scientific, Political, & Speculative Part 6
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